Read e-book online State-to-State Dynamical Research in the F+H2 Reaction PDF

By Zefeng Ren

This thesis addresses very important and likewise hard concerns within the examine of chemical response dynamics of F+H2 method. One is to probe the response resonance and the opposite is to figure out the level of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. the writer introduces a cutting-edge crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight technique, and provides thorough state-to-state experimental experiences to address the above concerns. the writer additionally describes the remark of the Feshbach resonance in the F+H2 reaction, a precise dimension of the differential go part in the F+HD response, and validation of a brand new actual strength strength floor with spectroscopic accuracy. additionally, the writer determines the reactivity ratio among the floor country F(2P3/2) and the excited country F*(2P1/2) in the F+D2 response, and exploits the breakdown of BOA within the low collision energy.

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State-to-State Dynamical Research in the F+H2 Reaction System (Springer Theses) by Zefeng Ren

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